PdCl2 (dtbpf)-CAS NO.:95408-45-0-Canan Material Co., Ltd

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PdCl2 (DtBPF)

Common Short Description:

PdCl2 (dtbpf)

CAS NO.:

95408-45-0

Molecular Weight:

651.75

Metal,% :

16.33%

Stablitity:

Application:

Molecular Formula：

C26H44Cl2FeP2Pd

Metal Type:

Palladium

Classification:

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Product Details

PdCl2 (dtbpf)

Chemcial Name: Dichloro[1,1’-bis(di-tert-butylphosphino)ferrocene]palladium(II); PdCl₂ (DtBPF)

Synonyms: 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride

CAS No.: 95408-45-0

Structure: PdCl2 (dtbpf), [1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II), 95408-45-0

Application:

The X-ray structure of (DtBPF)PdCl2 revealed the largest P-Pd-P bite angle (104.2 degrees ) for a ferrocenyl bisphosphine ligand. 31P NMR monitoring of (DtBPF)PdCl2-catalyzed reaction of 4-chlorotoluene with propiophenone indicated that DtBPF remained coordinated in a bidentate mode during the catalytic cycle.

This air stable, solid catalyst has demonstrated exemplary reactivity in α-arylations of various ketones with aryl chlorides and bromides and also performs strongly in Suzuki coupling reactions

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